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Jiao et al., Biochim Biophys Acta 1999 (Fatigue) : It is concluded that : ( 1 ) MnSO4 dependent glucose transfer to glycoproteins is catalyzed by a nonglucose 6-P dependent form of glycogen synthase; (2) MnSO4 dependent glycogen synthase has a greater affinity for low molecular mass glycoproteins and may thus play a more important role than glucose 6-P dependent glycogen synthase in the initial stages of glycogen biogenesis ; and ( 3 ) glycogenin is generally inactive in human muscle in vivo
Luttrell et al., Endocrinology 1986 (Insulin Resistance...) : All stimulated hexose transport, glucose incorporation into glycogen, and hexose dependent activation of glycogen synthase in a manner not additive with insulin, but none increased basal glycogen synthase I activity in the absence of hexose